Artificial Spin Ices and X-ray Orbital Angular Momentum
This research program seeks to understand fluctuations and phase transitions in artificial spin ices (ASIs), and to use this knowledge to study X-ray orbital angular momentum (OAM) generated by these structures. ASIs consist of patterned arrays of nanomagnets, as shown in (a) in the figure below, whose properties can be tuned based on geometry and competing interactions. ASIs are often designed to realize systems not readily accessible in nature such as geometrically frustrated magnetic lattices. ASIs can be reconfigured through a variety of field, temperature, and direct writing approaches. Control of these processes and the introduction of defects may allow ASIs to be programmed into states with useful functions such as magnetic logic or generation of X-ray OAM. OAM is a topological property of light for which the photon phase has a helical structure around its propagation axis. Interest in optical OAM is rapidly increasing in the X-ray regime where it could provide a selective probe of electronic and magnetic systems. ASIs can be patterned with topological defects and reconfigured dynamically. As a result, they offer a pathway to X-ray metamaterials for programmable OAM generation and a platform to deepen understanding of photon interactions with 2D magnetic lattices.
Experimental realization of a single-domain AF ground state in a square ASI with a double edge dislocation and resulting X-ray diffraction. (a) Scanning electron micrograph of a permalloy ASI with a topological defect consisting of a double edge dislocation. (b) XMCD-PEEM micrograph revealing the single-domain AF ground state order. The blue boxes trace out a Burgers circuit. (c) X-ray diffraction at the Fe L-edge resonance dramatically enhances vortex beams at the AF Bragg conditions (half-integer values of H and K) which carry odd-order OAM.
This research is supported by the U.S. Department of Energy office of Basic Energy Sciences under award DE-SC0016519.
Nanoscale 3D Priting and Machining with Electron Beams
Nearly all high-throughput nanomanufacturing processes require the replication of master templates. As a result, three barriers to manufacturability demand new solutions: (1) rapid prototyping before committing to a production template, (2) repair of template errors and defects both before and during production, and (3) product debugging before committing to revised templates. Locally adding ("printing") and subtracting ("machining") materials using a focused electron-beam could meet these needs if the available materials, purity, and throughput were not limited by the associated gas-phase reactants. This research project investigates a change from gas to liquid reactants in order to expand the range of processes and materials available and dramatically improve purity and throughput. These advances could enhance efficiency at multiple points in the product cycle for nanomanufactured systems.
(a) Nanoscale 3D printing using electron-beams in liquids. An aqueous solution typically serves as the precursor and remains liquid on a cooled substrate in a partial vacuum. Inset: “UK” logo patterned in copper on silicon. (b) A copper “nested-L” structure deposited from CuSO4, H2SO4, and polyethylene glycol (aq.) was featured on the cover of Nanotechnology. (c) A cross-sectional micrograph of a high aspect ratio copper structure. (d) Silver structures deposited on silicon from an aqueous solution of AgNO3.
This work is supported by award CMMI-1538650 from the National Science Foundation. Publically available data from the research effort is available here: CMMI-1538650 Data.
3D Optical Metasurfaces
Clean Hydrogen Generation by Coupling Plasmonic Nanoparticles to Phototrophic Bacteria (led by Prof. Bhattacharyya, UK Chemical Engr.)
Anti-viral Membrane Masks and Filters (led by Prof. Bhattacharyya, UK Chemical Engr.)